王大伟
编辑:    来源:   发布日期:2014-04-04  

 

一、个人简介                                                                   

 王大伟,男,19792月生,博士、副教授、硕士生导师。

20097月在中科院大学化学物理研究所获得博士学位,从200910月起在美国西弗吉尼亚大学(West Virginia University)从事博士后研究。20126月进入江南大学工作至今。

 二、 研究领域                                                                    

 1、借氢反应及其应用研究。

 2、醌类衍生物的合成及性质研究。

 3、主要从事唑膦配体的设计合成及其在催化反应中的应用。

 4、新型金催化剂设计合成及其催化反应研究

 三、学术成果                                                                      

(一)代表性科研项目

1、主持国家自然科学基金青年基金2014

2、主持江苏省“六大人才高峰”人才项目2013

3、主持教育部留学回国基金2013

4、主持江苏省自然科学基金青年基金2013

5、江苏省自然科学优秀学术论文二等奖 2015

 (二)代表性论文

1.Xiaoli Yu, Duo-Sheng Wang, Zhaojun Xu, Bobin Yang, and Dawei Wang,* The synthesis of unsymmetric diamides through Rh-catalyzed selective C-H bond activation of amides with isocyanates, Org. Chem. Front., 2017, 4, DOI: 10.1039/C6QO00793G.

2.Dawei Wang,* Xiaoli Yu, Xiang Xu, Bingyang Ge, Xiaoli Wang, Yaxuan Zhang, Non-coordinating Anion Directed Reversal of Activation Site: The Selective C-H Bond Activation Reaction of N-aryl rings, Chem. Eur. J. 2016, 22, 8663-8668.

3.Dawei Wang,* Xin Yu, Wei Yao, Wenkang Hu, Chenyang Ge, Xiaodong Shi,* Copper Catalyzed Reaction Cascade of Thiophenol Hydroxylation and S-Arylation through Disulfide Directed C-H Activation, Chem. Eur. J. 2016, 22, 5543-5546 (Hot Paper).

4.Yongchun Yang, Wenkang Hu, Xiaohan Ye, Dawei Wang,* and Xiaodong Shi,* Preparation of Triazole Gold(III) Complexes as Effective Catalyst for the Synthesis of E-α-Haloenones, Adv. Synth. Catal. 2016, 358, 2583-2588.

5.Yongchun Yang, Anni Qin, Keyan Zhao, Dawei Wang,* and Xiaodong Shi,* The Design and Synthesis of Alanine Triazole Ligand and Their Application in Promotion of Hydration, Allene Synthesis and Borrow Hydrogen Reaction, Adv. Synth. Catal. 2016, 358, 1433-1439.

6.Xiaoli Yu, Qiujin Wu, Huida Wan, Zhaojun Xu, Xingle Xu and Dawei Wang,* Copper and triphenylphosphine-promoted sulfenylation of quinones with arylsulfonyl chlorides, RSC Adv., 2016, 6, 62298-62301.

7.Xiaoli Yu, Bingyang Ge, Yaxuan Zhang, Xiaoli Wang, and Dawei Wang,* Silver-Mediated Phosphorylation of C(sp2)-H Bonds with P-H Bonds: Direct C-H Functionalization of Ferrocenyl Anilides and Phosphonate Esters under Pd and Cu Free Conditions, Asian J. Org. Chem. 2016, 5, 1253-1259.

8.Jianping Chen, Keyan Zhao, Bingyang Ge, Chongying Xu, Dawei Wang,* and Yuqiang Ding,* Iridium-Catalyzed Synthesis of Diaryl Ethers by Means of Chemoselective C-F Bond Activation and the Formation of B-F Bonds. Chem. Asian J. 2015, 10, 468-473.

9.Dawei Wang,* Keyan Zhao, Chongying Xu, Hongyan Miao, and Yuqiang Ding,* Synthesis, Structures of Benzoxazolyl Iridium(III) Complexes, and Applications on C−C and C−N Bond Formation Reactions under Solvent-Free Conditions: Catalytic Activity Enhanced by Noncoordinating Anion without Silver Effect, ACS Catal. 2014, 4, 3910-3918.

10.Dawei Wang,* Bingyang Ge, Liang Li, Jie Shan, and Yuqiang Ding,* Transition Metal-Free Direct C−H Functionalization of Quinones and Naphthoquinones with Diaryliodonium Salts: Synthesis of Aryl Naphthoquinones as β‑Secretase Inhibitors, J. Org. Chem. 2014, 79, 8607-8613.

11.Dawei Wang,* Keyan Zhao, Xin Yu, Hongyan Miao and Yuqiang Ding,* Iridium–CNP complex catalyzed cross-coupling of primary alcohols and secondary alcohols by a borrowing hydrogen strategy, RSC Adv., 2014, 4, 42924-42929.

 

Before 2013

12.Dawei Wang, Rong Cai, Sripadh Sharma, James Jirak, Sravan K. Thummanapelli, Novruz G. Akhmedov, Hui Zhang, Xingbo Liu, Jeffrey L. Petersen, Xiaodong Shi*, “Silver Effect” in Iridium(I) Catalysis: An Overlooked Important Factor, J. Am. Chem. Soc. 2012, 134, 9012−9019.

13.Dawei Wang, Lekh Nath S. Gautam, Cynthia Bollinger, Alexandria Harris, Minyong Li, Xiaodong Shi*. 1,2,3-Triazole Bound Au(I) (TA-Au) as Chemoselective Catalysts in Promoting Asymmetric Synthesis of Substituted Allenes. Org. Lett. 2011, 13, 2618-2621.

14.Dawei Wang, Yanwei Zhang, Alexandria Harris, Lekh Nath S. Gautam, Yunfeng, Chen, Xiaodong Shi*. Triazole-Au Promoted Effective Synthesis of Enone from Propargyl-Esters and Alcohols: a Catalyst Offered Chemo-Selectivity, Acidity and Ligand Economy. Adv. Synth. Catal. 2011, 353, 2584-2588.

15.Dawei Wang, Xiaohan Ye, Xiaodong Shi*. Efficient Synthesis of E-Haloenones Through Chemoselective Alkyne Activation Over Allene with Triazole-Au Catalysts. Org. Lett. 2010, 12, 2088-2091.

16.Da-Wei Wang, Duo-Sheng Wang, Qing-An Chen, Yong-Gui Zhou*. Asymmetric Hydrogenation with Water/Silane as the Hydrogen Source. Chem. Eur. J. 2010, 16, 1133-1136.

17.Da-Wei Wang, Yong-Gui Zhou*, Qing-An Chen and Duo-Sheng Wang, Chapter 10: Enantioselective Reduction of Nitrogen-based Heteroaromatic Compounds, Page 299-339, in Chiral Amine Synthesis, Editor: Thomas C. Nugent, Wiley-VCH, 2010.4.20.

18.Da-Wei Wang, Xiao-Bing Wang, Duo-Sheng Wang, Sheng-Mei Lu, Yong-Gui Zhou*, Yu-Xue Li*. Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines. J. Org. Chem. 2009, 74, 2780-2787.

四、联系方式                                                                     

通讯地址:无锡市蠡湖大道1800号 江南大学化学与材料工程学院

邮编:214122

联系电话:13382888529

Email: wangdw@jiangnan.edu.cn, wwangdawei@163.com

                   

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